摘要
The solvothermal reaction (D2O) of 2,6-dideuterium-4-cyanopyridine with ZnCl2 in the presence of NaN3 offers a novel complex Zn(OD)(C6H2D2N4) (1) in which Zn has a distorted tetrahedron composed of two N atoms from one tetrazoyl group and pyridyl group and two O atoms from two deuteratohydroxy OD groups. Crystal data for 1:Pbcn, a=1.456 8(5) nm, b=0.659 2(2) nm, c=1.645 3(5) nm, α=90°, β=90°, γ=90°, V=1.580 0(9) nm3, Z=8, M=231.54, Dc=2.236 Mg·m-3, μ=3.070 mm-1, R1=0.043 4, wR2=0.120 6, S=1.029. CCDC:660629.
The solvothermal reaction （D2O） of 2,6-dideuterium-4-cyanopyridine with ZnCl2 in the presence of NaN3 offers a novel complex Zn（OD）（C6H2D2N4） （1） in which Zn has a distorted tetrahedron composed of two N atoms from one tetrazoyl group and pyridyl group and two O atoms from two deuteratohydroxy OD groups. Crystal data for 1：Pbcn, a=1.456 8（5） nm, b=0.659 2（2） nm, c=1.645 3（5） nm, α=90°, β=90°, γ=90°, V=1.580 0（9） nm^3, Z=8, M=231.54, Dc=2.236 Mg·m^-3, μ=3.070 mm^-1, R1=0.043 4, wR2=0.120 6, S=1.029. CCDC：660629.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第11期1997-1998,共2页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.50673039,20471029,20490214)
关键词
氘
锌(Ⅱ)配合物
溶剂热合成
晶体结构
deuterium
zinc（Ⅱ） complex
solvothermal reaction
crystal structure
