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A new sesquiterpene from Caragana intermediia 被引量:3

A new sesquiterpene from Caragana intermediia
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摘要 A new alloaromadendrane-type sesquiterpene, (-)-alloaromadendrane-3β,9β-diol (1), has been isolated from the aerial part of Caragana intermediia. The structure of (-)-alloaromadendrane-3β,9β-diol (1) was established by spectroscopic methods, including X-ray analysis that provided its relative stereochemistry. Bioassay showed that (-)-alloaromadendrane-3β,9β-diol (1) possesses anti-pyricularia oryzae P-2b activity with MIC value of 10 μg/m-L. A new alloaromadendrane-type sesquiterpene, (-)-alloaromadendrane-3β,9β-diol (1), has been isolated from the aerial part of Caragana intermediia. The structure of (-)-alloaromadendrane-3β,9β-diol (1) was established by spectroscopic methods, including X-ray analysis that provided its relative stereochemistry. Bioassay showed that (-)-alloaromadendrane-3β,9β-diol (1) possesses anti-pyricularia oryzae P-2b activity with MIC value of 10 μg/m-L.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第11期1379-1382,共4页 中国化学快报(英文版)
基金 supported by the National Natural Science Foundation of China(No.30 070 085) partly supported by the startup fund of Northwest A&F University for Talent(No.01140410).
关键词 Caragana intermediia LEGUMINOSAE Sesquitetpene (-)-Alloaromadendrane-3β 9β-diol Caragana intermediia Leguminosae Sesquitetpene (-)-Alloaromadendrane-3β,9β-diol
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参考文献9

  • 1[1]Y.Zhao,Acta Ecol.Sin.25 (12) (2005) 3411.
  • 2[2]Jiangsu New Medical College,Dictionary of Chinese Traditional Medicine,Shanghai Science and Technology Press,Shanghai,1985,p.1019.
  • 3[3]The aerial parts of Caragana intermediia was collected from the south of Gansu province,P.R.China in May 2001.The specimen was identified by Professor Yingxing Liu at Institute of Lanzhou Desert,Chinese Academy of Sciences.Duplicate voucher specimens (Voucher number:No.1Chenqinsheng Lanzhou) have been deposited in Institute of Lanzhou Desert,Chinese Academy of Sciences.
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  • 8[8]Crystallographic data has beendeposited at the Cambridge Crystallographic Data Center (CCDC) (deposition number CCDC 629115).These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html.(or from the CCDC,12 Union Road,Cambridge CB21EZ,UK; fax:+44 1223 336033; e-mail:deposit@ccdc.cam.ac.uk).
  • 9[9]H.Kobayashi,M.Namikoshi,T.Yoshimoto,J.Antibiot.49 (9) (1996) 873.

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