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三相电极法研究液/液界面离子转移的进展

The progress in the study of ion transfer reaction at liquid-liquid interface by three-phase electrode
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摘要 三相电极法作为研究液/液界面离子转移的一种新方法,具有简单、快速、经济的特点。文章回顾了液/液界面离子转移的发展历史,介绍了三相电极法的实验原理,并对其在电化学中的研究进展和应用进行了评述,引用文献48篇。 Three-phase electrode is a new access to study ion transfer reaction across liquid-liquid interface. It has many advantages such as simplicity ,rapidity,economy. This paper dated back the history of ion transfer at the liquid-liquid interface,and introduced the experimental principle of this new method. A brief review about the proress and the application of the study in electrochemistry had been given. 48 papers were cited.
作者 刘秀辉 杨俊 卢小泉
机构地区 西北师范大学化学化工学院
出处 《化学研究与应用》 CAS CSCD 北大核心 2007年第11期1185-1190,共6页 Chemical Research and Application
基金 国家自然科学基金资助项目(20335030) 甘肃省自然科学基金资助项目(3ZS051-A25-023) 甘隶省高分子材料重点实验室资助项目
关键词 液/液界面 离子转移 三相电极法 liquid-liquid interface ion transfer reaction three-phase electrode
分类号 O621.261 [理学—有机化学]
  • 相关文献

参考文献48

  • 1Marcus Y, Kertes A S. in Ion Exchange and Solvent Extraction of Metal Complexes, New York: Wileyinterscience, 1969.
  • 2Honig B H,Hubbell W L, Flewelling R F. Electrostatic interactions in membranes and proteins. Annu. Rev. Biophys. Biophys, Chem. ,1986,15:163-193.
  • 3Starks C M, Liotia C L, Halpem M. Phase Transfer Catalysis,New York:Chapman and Hall ,1994.
  • 4Girault H H. Modern Aspects of Electrochemistry, New York: Plenum, 1993,25 : 1-62.
  • 5Samec Z. Charge transfer between two immiscible electrolyte solutions. Advance in method of electrolysis with the electrolyte dropping electrode (EDE) [J]. Electroanal Chem., 1979,99:385-389.
  • 6Samec Z. Charge transfer between two immiscible electrolyre solutions. Part Ⅱ. The Inevsfigation of the Cs + ion transfer across the nitrobenzenz/water interface by cyclic voltammetry With IR drop compensation [ J ]. Electroanal Chem. ,1979,100:841-852.
  • 7Kakutani, Osakai T, Senda M. A potential-step chronoamperometric study of ion transfer at the water/nitrobenzene interface [J]. Bull. Chem. Soc. Jpn., 1983, 56:991-996.
  • 8Homolke D, Marecek V. Charge transfer between two immiscible electrolyte solutions:Part Ⅵ. Polarographic and vohammetric study of picrate ion transfer across the water/ nitrobenzene interface [ J ]. Electroanal Chem. , 1980,110 : 91-96.
  • 9Samec Z, Marecek V, Homolke D. The double layer at the interface between two immiscible electrolyte solution:part Ⅰ capacity of the water/nitrobenzene interface [ J ]. Electroanal Chem. , 1981,126 : 121-19.
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二级参考文献56

  • 1王旵明,俞泽穆,汪尔康.两种喹啉类药物在水/硝基苯界面循环伏安研究[J].化学学报,1994,52(1):76-82. 被引量：5
  • 2《化学通报》网络版(ChemistryOnline)2006年第2期论文摘要[J].化学通报,2006,69(2):158-160. 被引量：54
  • 3[1]Girault H H. Charge Transfer Across Liquid-Liquid Interfaces. In: Bockris J O'M, Conway B E, White R E, eds. Modern Aspects of Electrochemistry. New York: Plenum Press, 1993. 1
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  • 5[3]Girault H H, Schiffrin D J. Electrochemistry of liquid-liquid interfaces. In: Bard A J, ed. Electroanalytical Chemistry, Vol 15, New York: Marcel Dekker, 1989
  • 6[4]Samec Z, Kakiuchi T. Charge transfer kinetics at water-organic solvent phase boundaries. In: Gerischer H, Tobias C W, eds. Advances in Electrochemistry and Electrochemical Engineering. Weinheim: VCH, 1995. 300～356
  • 7[5]Samec Z, Marecek V, Weber J. Charge transfer between two immiscible electrolyte solutions. Part II. The investigation of cesium(1+) ion transfer across the nitrobenzene/water interface by cyclic voltammetry with IR drop compensation. J Electroanal Chem, 1979, 100: 841～852
  • 8[6]Taylor G, Girault H H. Ion transfer reactions across a liquid-liquid interface supported on a micropipette tip. J Electroanal Chem, 1986, 208(1): 179～183
  • 9[7]Shao Y, Mirkin M V. Fast kinetic measurements with nanometer-sized pipets. Transfer of potassium ion from water into dichloroethane facilitated by dibenzo-18-crown-6. J Am Chem Soc, 1997, 119(34): 8103～8104
  • 10[8]Campbell J A, Girault H H. Steady-state current for ion transfer reactions at a micro-liquid/liquid interface. J Electroanal Chem, 1989, 266(2): 465～469

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化学研究与应用
2007年 第11期

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