摘要
利用自洽平均场理论(SCMFT)系统地研究了对称长链和近对称短链两嵌段聚合物混合体系在纳米尺度下的自组装行为.体系中具有较高聚合度的对称长链熔体处于层状相,聚合度较低的近对称短链熔体处于无序相,而其混合体系却随着两种成分的不同比例呈现出有序-无序相转变、有序-有序相转变及有序-无序两相共存等复杂的相行为,计算结果与近期类似体系的实验有着较好的吻合.同时与两种对称的两嵌段聚合物混合体系的计算结果进行了比较,得出这两种体系的异同之处.
The phase behavior of binary blends of symmetric long diblock copolymers and nearly short symmetric diblock copolymers with different ratio of chain lengths is studied using the self-consistent field theory. The occurrence of order-order transition, disorder-order transition and regions of order-disorder coexistence has been examined. Comparisons are also made with the theoretical study of the binary blend of symmetric long and short diblock copolymers and experiments on the similar systems. The effects of the short nearly symmetric diblock copolymer on the symmetric long diblock copolymer in their blends were analyzed.
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
2007年第11期1035-1039,共5页
Acta Polymerica Sinica
基金
国家自然科学基金(基金号20474034
20274020
20374031
20373029)
高等学校骨干教师资助计划(项目号GG-703-10055-1008)资助项目