摘要
以12-钨磷酸和二苯胺为原料合成了一种电荷转移盐。通过元素分析确定其组成为[(C6H5)2NH2]3[PW12O40]·4H2O,各元素的质量分数分别为(括号内为理论值)C 12.91%(13.08%),H 1.304%(1.344%),N 1.793%(1.793%),采用红外光谱、紫外.可见分光光度法、X射线粉末衍射等测试技术对该化合物进行了分析表征。结果表明:所合成的新型电荷转移化合物的杂多阴离子保持Keggin结构特征。
A charge transfer salt was synthesized with 12-tungstenphosp horic acid and diphenylamine in aqueous solution. It's molecular formula was determined as [(C6H5)2NH2]3[PW12O40]· 4H2O by element analysis. The mass fractions of elements are (the numbers in bracket are theoretical values) C 12.91%(13.08%), H 1.304%(1.344%), N 1.793%(1.793%). The compound was characterized by X-ray powder diffraction analysis, IR and UV-Vis spectrophotometry. The results indicate that it keeps the Keggin structure of anion, but the Keggin structure is more or less transformed under the influence of diphenylamine.
出处
《功能材料》
EI
CAS
CSCD
北大核心
2007年第A10期4003-4005,共3页
Journal of Functional Materials
基金
山西科委攻关资助项目(20021109)
关键词
12-钨磷酸
二苯胺
电荷转移盐
合成
表征
12-tungstenphosphoricacid
diphenylamine
charge-transfer salt
synthesis
characterization