β—二酮亚胺—铁(Ⅱ)羰基配合物的合成及其表征

Synthesis and Structural Characterization of β Diketiminate Iron(Ⅱ) Carbonyl

β-二酮亚胺配体(ArN(R)CCH(R)NAr,R=CH_3,H,Ar=2,6-二异丙基苯胺,苯胺,2,6-二甲基苯胺等等)可与不同金属配位形成多种配合物,上述配合物因其特殊的反应性能引起了研究者的广泛关注。本文以环戊二烯氯代羰基铁与β-二酮亚胺配体(ArN (R)CCH(R)NAr,R=CH_3,Ar=2,6-二甲基苯胺)反应生成铁的金属配合物,并对其产物进行了IR,1HNMR表征。

β-diketiminato （ArN （R） CCHC （R）NAr-, R=CH3, H, Al=-2,6-diisopropylphenyl, aniline, 2,6-dimethyl phenyl） has led to much current interest for its coordinate variation. In this paper, we reported preparation and characterized new β-diketiminato complex containing the carbonyl-iron part. All the compounds including ligand and final complex were characterized by IR and 1HNMR.