摘要
Metal zirconium was prepared by electro-deoxidization method. Using CaCl2 molten salt as electrolyte,sintered ZrO2 pallets as cathode,graphite rod as anode,the pallets were electrolyzed at 900 ℃ and 3.1 V for 8,10 and 12 h,respectively. The mechanism of electro-deoxidization of ZrO2 was studied preliminarily. The results show that the morphologies of cathode pallets affect the forming process of products. The process of electro-deoxidization of ZrO2 in the molten salt is conducted step by step,from exterior of cathode to its interior and from high valence oxide to low valence oxide until to metal.
Metal zirconium was prepared by electro-deoxidization method. Using CaCl2 molten salt as electrolyte, sintered ZrO2 pallets as cathode, graphite rod as anode, the pallets were electrolyzed at 900 ℃ and 3.1 V for 8, 10 and 12 h, respectively. The mechanism of electro-deoxidization of ZrO2 was studied preliminarily. The results show that the morphologies of cathode pallets affect the forming process of products. The process of electro-deoxidization ofZrO2 in the molten salt is conducted step by step, from exterior of cathode to its interior and from high valence oxide to low valence oxide until to metal.
出处
《中国有色金属学会会刊：英文版》
CSCD
2007年第A01期560-564,共5页
Transactions of Nonferrous Metals Society of China
基金
Project (50434030) supported by the National Natural Science Foundation of China
Project(2007CB613801) supported by the State Basic Research Program of China
