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Low-temperature performance and high-rate discharge capability of AB_5-type non-stoichiometric hydrogen storage alloy 被引量:1

Low-temperature performance and high-rate discharge capability of AB_5-type non-stoichiometric hydrogen storage alloy
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摘要 Low-temperature performance and high-rate discharge capability of AB5-type non-stoichiometric hydrogen storage are studied. X-ray diffraction(XRD),pressure-composition-temperature(PCT) curves and electrochemical impedance spectroscopy(EIS) are applied to characterize the electrochemical properties of ABx(x=4.8,4.9,5.0,5.1,5.2) alloys. The results show that the non-stoichiometric alloys exhibit better electrochemical properties compared with that of the AB5 alloy. Low-temperature performance and high-rate discharge capability of AB5-type non-stoichiometric hydrogen storage are studied. X-ray diffraction(XRD), pressure-composition-temperature(PCT) curves and electrochemical impedance spectroscopy(EIS) are applied to characterize the electrochemical properties of ABx (x=4.8, 4.9, 5.0, 5.1, 5.2) alloys. The results show that the non-stoichiometric alloys exhibit better electrochemical properties compared with that of the AB5 alloy.
出处 《中国有色金属学会会刊:英文版》 CSCD 2007年第A02期978-984,共7页 Transactions of Nonferrous Metals Society of China
基金 Project(2006AA11A151) supported by the National Hi-Tech Research and Development Program of China
关键词 储氢合金 化学计量学 低温性能 放电容量 AB5-type hydrogen storage alloy non-stoichiometry low-temperature performance high-rate discharge capability
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  • 1TLIHA M, KHALDI C, MATHLOUTHI H, LAMLOUMI J, PERCHERON-GUEGAN A. Electrochemical investigation of the iron-containing and no iron-containing AB5-type negative electrodes [J]. J Alloys Compd, 2007, 440(1/2): 323-327.
  • 2RIVERA M A, PAL U, WANG Xian-you, GONZALEZ- RODRIGUEZ J G, GAMBOA S A. Rapid activation of MmNis-xMx based MH alloy through Pd nanoparticle impregnation [J]. J Power Sources, 2006, 155: 470-474.
  • 3LI Rong, WU Jian-min, SU Hang, ZHOU Shao-xiong. Micro- structure and electrochemical performance of vanadium-containing AB5-type low-Co intermetallic hydrides [J]. J Alloys Compd, 2006, 421: 258-267.
  • 4YUAN Xian-xia, XU Nai-xin. Determination of hydrogen diffusion coefficient in metal hydride electrode by cyclic voltammetry [J]. J Alloys Compd, 2001, 316(1/2): 113-117.
  • 5LI Shang, PAN Gui-ling, ZHANG Ying, GAO Xue-ping, QU Jing-qiu, YAN Jie, WU Feng, SONG De-ying. Electrochemical properties of MmNi3.6Co0.7Al0.3Mn0.4 alloy containing carbon nanotubes [J]. J Alloys Compd, 2003, 353: 295-300.
  • 6IWAKURA C, OURA T, INOUE H, MATSUOKA M, YAMAMOTO Y. Effect of alloy composition on hydrogen diffusion in the AB5-type hydrogen storage alloys [J]. J Electroanal Chem, 1995, 398(1/2): 37-41.
  • 7YU X B, FENG S L, WU Z, XIA B J, XU N X. Hydrogen storage performance of Ti-V-based BCC phase alloys with various Fe content [J]. J Alloys Compd, 2005, 393: 128-134.
  • 8VALФEN i O, LASIA A, JENSEN J O, TUNOLD R. The electrochemical impedance of metal hydride electrodes [J]. Electrochimica Acta, 2002, 47:2871-2884.
  • 9YUAN Xian-xia, XU Nai-xin. Determination of hydrogen diffusion coefficient in metal hydride electrode by modified Warburg impedance [J]. J Alloys Compd 2001,329:115-200.
  • 10RAJU M, MANIMARAN K, ANANTH M V, RENGANATHAN N G. An EIS study on the capacity fades in MmNi3.6Al0.4Mn0.3Co0.7 metal-hydride electrodes [J]. Int J Hydrogen Energy, 2007, 32: 1721-1727.

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