摘要
The molecular-based magnetic complex {[Cu (1, 3-Pn )]2 [Fe (CN)6] (OH).3H2O }n, where 1, 3-Pn is 1, 3-diaminopropane, has been prepared and characterized by X-raycrystallography. It crystallizes in the monoclinic system, space group P21 /n, with a =0. 757 7(3) nm, b=1. 069 8(1) nm, c=1. 300 0(2) nm, β=90. O5°, V=1. 053 8(5) nm3,and Z =4. The result of the crystallography indicates that this complex has a three-dimen-sional structure.
The molecular-based magnetic complex {[Cu (1, 3-Pn )]2 [Fe (CN)6] (OH).3H2O }n, where 1, 3-Pn is 1, 3-diaminopropane, has been prepared and characterized by X-raycrystallography. It crystallizes in the monoclinic system, space group P21 /n, with a =0. 757 7(3) nm, b=1. 069 8(1) nm, c=1. 300 0(2) nm, β=90. O5°, V=1. 053 8(5) nm3,and Z =4. The result of the crystallography indicates that this complex has a three-dimen-sional structure.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1997年第7期1018-1021,共4页
Chemical Journal of Chinese Universities
基金
南京大学配位化学国家重点实验资助
关键词
异双金属氰化物
混合桥
无序
三维结构
合成
Three-dimensional structure, Hetero-bimetallic cyano complex, Mixed-bridge,Disorder
