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NBT-KBT-BT系弛豫铁电体的弥散相变研究 被引量:4

Investigation on Diffuse Phase Transition of NBT-KBT-BT Ferroelectric Relaxors
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摘要 采用传统压电陶瓷固相合成法制得纯钙钛矿相的(1.002-5x)NBT-4xKBT-(x-0.002)BT(x=0.026,0.028,0.030,0.032,0.034)(简写为BNBKT100x)系弛豫铁电体。通过X-射线衍射(XRD)分析,当x=0.030时为三方、四方两相共存,为该体系的准同型相界。系列样品的介电温谱显示在室温到500℃之间存在两个介电反常峰,分别对应于陶瓷材料的铁电-反铁电-顺电相变。同时发现该系列样品显示出弛豫铁电体特性。并用成分起伏理论解释了这种弛豫弥散相变。 (1. 002 -- 5x) NBT-4x KBT-(x- 0. 002) BT (x = 0. 026,0. 028,0. 030,0. 032,0. 034) (abbr. as BNBKT100x) lead-free ceramics systems were prepared by conventional solid-state ceramics preparation method. XRD resust show that the crystalline structure of the investigated materials were single perovskite. The morphotropic phase bounday (MPB)of the system between rhombohedral and tetragonal locates about at x=0. 030. The dielectric properties of BNBKT100x samples from room temperature to 500 ℃ at different frequencies and at 1 kHz were studied . Two dielectric constant abnormal peaks exists,which corresponding to the phase transition of ferroelectric to antiferroelectric and antiferroelectric to paraelectric phase. It was also found that in the compositions thus prepared were all ferroelectric relaxors. And the causes of diffuse phase transition were interpreted by The theory of heterophase fluctuation .
出处 《压电与声光》 CSCD 北大核心 2007年第6期713-716,共4页 Piezoelectrics & Acoustooptics
基金 西安应用材料创新基金资助项目(XA-AM-200715) 西安市科技创新支撑计划资助项目(YF07062)
关键词 钛酸铋钠 钛酸铋钾 钛酸钡 弛豫铁电体 弥散相变 sodium-bismuth titanate potassium-bismuth titanate barium titanate ferroelectric relaxors diffuse phase transition
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参考文献14

  • 1SMOLENSKII G A, ISUPOV V A, AGRANOVSKAYA A I. Ferroelectrics with diffusephase transition[J]. Sov Phys Solid State,1961(2):2 584- 2 594.
  • 2AKSENOV V L,DIDYK A Y. Structure phase transition in solid solution[J]. Ferroelectrics, 1983 (48) : 9- 15.
  • 3王新荣,张孝文.94全国结构陶瓷、功能陶瓷、金属/陶瓷封接学术会议论文集[C].北京:中国硅酸盐学会特种陶瓷专业委员会等,1994:5759.
  • 4SMOLENSKII G A, ISUPOV V A, AGRANOVSKAYA A I, et al. New ferroelectrics of complex composition [J]. Sov Plays Solid STATE, 1961,2 ( 11 ) : 2 651- 2 654.
  • 5TAKENAKA T, MARURAMAK I. Na0.5Bi0.5TiO3-BaTiO3 system for lead free piezoelectric ceramics[J]. Jpn J Appl Phys,1991,30(9B) :2 236- 2 239.
  • 6PRONIN I P,SVMIKOV P P,ISUPOV V A,et al. Peculiarties of phase transition in sodium bismuth titanate [J]. Ferroelectrics,1980,25:395 -397.
  • 7SAKATA K, TAKENAKA T, NAITON Y. Phase relations, dielectric and piezoelectric properties of ceram ics in the eyetem Na0.5 Bi0.5TiO3-PbTiO3[J]. Ferroelectrics, 1992,131 : 219-226.
  • 8李月明,陈文,徐庆,周静,廖梅松.Na_(0.5)Bi_(0.5)TiO_3-K_(0.5)Bi_(0.5)TiO_3系铁电体的相变研究[J].功能材料,2004,35(3):341-343. 被引量:11
  • 9SMOLENSKY G A,ISUPOV V A. Phase changes of certain solid solutions having electrical properties of rachelle salt[J]. Dokl Akad Nank, USSR, 1954,96: 53- 54.
  • 10CROSS L E. Relaxor ferroelectrics[J]. Ferroelectrics,1987, 76:241-267.

二级参考文献15

  • 1王天宝 王列娥 等.硅酸盐学报,1986,14(1):14-22.
  • 2Smolenskii G A, Isupv V A, Afranovskaya A I. [ J ]. Soy Phys Solid St, 1961,2: 2651-2654.
  • 3Sasaki A, Chiba T, Mamiya Y, et al. [J]. Jap J Appl Phys, 1999,38: 5564-5567.
  • 4Nagata H, Takanaka T. [J]. Jap J Appl Phys, 1997, 36: 6055-6057.
  • 5Takanaka T, Maruyama K I, Sakata K. [J]. Jap J Appl Phy, 1991,30(9B): 2236-2239.
  • 6Sakatak K, Takenaka T, Naitou Y. [J]. Ferroelectrics, 1992, 131:219-216.
  • 7SuchaniczJ. [J]. Ferroelectrics ,1995, 172:455-548.
  • 8Suchanicz J. [J]. Ferroelectrics, 1998, 209:561-568.
  • 9Smolenskii G A, Isupov V A, Agranovskayy A I,et al. [ J ]. Soy Phys Sol Stat, 1961,2: 2584-2589.
  • 10Kreisel J, Glazer A M, Bouvier P, et al. [ J ]. Physical Review B,2001,63:1-10.

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