水杨醛缩氨基酸、联吡啶配合物的电化学合成

Electrochemical synthesis of complexes with a schiff base ligand from salicylidene and L-phenylalanine and 2,2'-bipyridine

以水杨醛缩L-苯丙氨基酸Schiff碱和2,2′-联吡啶为配体的非水溶剂中,用金属Cu、Zn、Ni为"牺牲"阳极,用电化学方法电解合成了Cu(Ⅱ)、Zn(Ⅱ)、Ni(Ⅱ)配合物.讨论了电化学合成的主要影响因素.通过元素分析、红外光谱、紫外光谱、热分析等对配体和配合物进行了表征,确定了配合物的化学组成,同时测定了Ni(Ⅱ)配合物的电化学性质.

Cu（Ⅱ）、Zn（Ⅱ） and Ni（Ⅱ） Mixed Coordination complexes of salicylideneamino acid and 2,2′-bipyridine were accomplished by electrochemical dissolution of sacrificial anodic metal Cu、Zn and Ni in non-aqueous solvent containing ligand salicylideneamino acid and 2,2′-bipyridine.Main influencing factors of electrochemical synthesis was discussed.The complexes were characterized by FT-IR,elemental analysis,UV-Visible Spectra,thermal analysis and so on.Complex components have been determined.And electrochemical property of Ni（Ⅱ） complex was examined.