期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

水对P_2O_5-SiO_2系玻璃质子导电性能的影响 被引量：2

Influence of water on proton conductivity of P_2O_5-SiO_2 system glass
下载PDF
导出
摘要 利用sol—gel法制备了P2O5-SiO2系质子导电玻璃。扫描电镜分析发现P2O5-SiO2玻璃具有微孔结构，并分析了特定条件下水对玻璃质子电导率的影响。结果表明：其质子电导率的对数，随吸水浓度对数值的增加而呈线性增加，直至吸水量达到饱和，在30℃，RH为30％条件下，电导率为10^-4～100S·cm^-1。 Protonic conductive P2O5-SiO2 system glasses were prepared with sol-gel processing. The glass＇s micro-structure was characterized by SEM. Influence of water on its conductivity was analyzed in given conditions. Results show that logarithm of proton conductivity exhibites a linear increase with increasing logarithm of concentration of water, till the content of water reaches saturation. The proton conductivity can reach 10^-4-10^-3 S · cm^-1 at 30 ℃, RH=30%.
作者 于宝刚
机构地区 中国人民武装警察部队学院科研部
出处 《电子元件与材料》 CAS CSCD 北大核心 2007年第12期18-20,共3页 Electronic Components And Materials
关键词 无机非金属材料 sol—gel法 P2O5-SiO2系玻璃 质子导电性 non-metallic inorganic material sol-gel processing P2O5-SiO2 system glass proton conductivity
分类号 TN604 [电子电信—电路与系统]
  • 相关文献

参考文献7

  • 1Janik M J, Canpbell, Kimberly A, et al. A computational and experimental study of anhydrous phosphotungstic acid and its interaction with water molecules [J]. Appl Catal A, 2003, 256(1): 51-69.
  • 2Pizzio L R, Vazquez P G, Caceres C V, et al. Supported keggin type heteropolycompounds for ccofriendly reactions [J]. Appl Catal A, 2003, 256: 125--140.
  • 3于宝刚,李启甲,殷海荣.氢燃料电池电解质P_2O_5-SiO_2快质子导电玻璃的Sol-Gel法合成[J].材料科学与工程学报,2004,22(5):742-745. 被引量：7
  • 4李启甲,于宝刚,殷海荣,张亚萍.溶胶-凝胶法制备P_2O_5-SiO_2快质子导电玻璃[J].玻璃与搪瓷,2004,32(1):27-30. 被引量：7
  • 5Masayuki N, Yoichi G, Yasushi T. Effect of phosphorus ions on the proton conductivity in the sol-gel-derived porous glasses [J]. J Am Cera Soc, 2001, 84(11): 2253-2256.
  • 6Masayuki N, Yoshihiro A. Evidence of water-cooperative proton conduction in silica glasses [J]. Phys Rev B, 1997, 5(1): 12108-12112.
  • 7Kreuer K D. On the complexity of proton conduction phenomena [J]. Solid State Ionics, 2000, 136(11): 149-160.

二级参考文献7

  • 1清山哲O.金属氧化物及其催化作用[M].合肥：中国科学技术出版社,1991.113-149.
  • 2野上正行.高プロトソ伝導ガラス[J].工業材料,2002,50(3):43-46.
  • 3A. Matsuda,Y. Matsuno,M. Tatsumisago et al. Fine patterning and characterization of gel films derived from methyltriethoxysilane and tetraethoxysilane [ J ]. C hem. Lett. , 1998,81 ( 11 ): 2849 ～ 2852.
  • 4Y. Daiko,T. Akai, T. Kasuga et al. Remarkable high proton conducting P2 O5 -SiO2 glass at a fuel cell electrolyte working at Sub-Zero to 120 ℃[J]. J. Jap. Ceram. Soc., 2001,109(10): 815～ 817.
  • 5Y. Abe, H. Shimakawa, L. L. Hench. Protonic conduction in oxide glass: simple relation between electrical conductivity activation energy, and the O-H bonding state [J]. Phys. Rev. B., 1988, 38(14): 10166 ～ 10169.
  • 6H. Scholze. Glastech. Ber. [M]Americ,1959,81～88.
  • 7Y. Abe, G. Li, M. Nogami, et al. Superprotonic Conductors of Glassy Zirconium Phosphate [J]. J. Electrochem. Soc., 1996, 143(1): 144～ 147.

共引文献11

同被引文献22

  • 1于宝刚,李启甲,殷海荣.氢燃料电池电解质P_2O_5-SiO_2快质子导电玻璃的Sol-Gel法合成[J].材料科学与工程学报,2004,22(5):742-745. 被引量：7
  • 2Vito D N,Rocco G,Enrico Negro,et al.Hybrid inorganic-organic proton conducting membranes based on Nafion and 5 wt% of MxOy (M=Ti,Zr,Hf,Ta and W):Part I Synthesis,properties and vibrational studies[J].Electrochim Acta,2007,53(4):1618-1627.
  • 3Pasierb P,Wierzbicka M,Komornicki S,et al.Structural,electrical and transport properties of yttrium-doped proton-conducting strontium cerates[J].J Power Sources,2007,173(2):681-687.
  • 4Lin Y F,Yen C Y,Chen C M,et al.High proton-conducting Nafion/-SO3H functionalized mesoporous silica composite membranes[J].J Power Sources,2007,171(2):388-395.
  • 5Uchida N,Ishiyama N,Kato Z,et al.Chemical effects of DCCA to the sol-gel reaction process[J].J Mater Sci,1994,29:5188-5192.
  • 6Viart N,Rehspringer J L.Study of the action of formamide on the evolution of a sol by pH measurements and fourier transformed infra-red spectroscopy[J].J Non-cryst Solids,1996,195,223-231.
  • 7Muha G. M., Vaughan PA.. J. Chem. Phys.[J]..1960, 33:194-199.
  • 8Szu S. P., Klein LC., Greenblatt M.. J. Non-Cryst. Solids[J]..1992, 143:21-30.
  • 9Fernández-Lorenzo C., Esquivias L, Barbroux P.. J. Non-Cryst. Solids[J]..1994, 176:189-199.
  • 10Krawietz T. R., Lin P., Lotterhos K. E.. J. Am. Chem. Soc.[J], 1998, 120: 8502-8511.

引证文献2

二级引证文献1

电子元件与材料
2007年 第12期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部