摘要
A new metal-organic coordination complex [Zn（H2BPTC）（phen）2]n.3nH2O （BPTC = 3,3＇,4,4＇-benzophenone tetracarboxylate, phen = 1,10-phenanthroline） 1 has been obtained from hydrothermal reaction and characterized by elementaj analysis, IR, TG and single-crystal X-ray diffraction. In compound 1, the zinc cation is hexa-coordinated with two carboxylate oxygen atoms from one H2BPTC ligand and four nitrogen atoms from two different phen ligands, showing a slightly distorted octahedral geometry. Crystal data： C41H30N4O12Zn, Mr = 836.06, monoclinic, P21/c, a = 14.2714（9）, b = 16.9386（10）, c = 15.0151（9）A, β = 101.3420（10）^o, V= 3558.8（4）A3 Dc = 1.560 g/cm^3,μ（MoKa） = 0.766 mm^-1, F（000） = 1720, Z= 4, R = 0.0439 and wR = 0.1157 for 4123 observed reflections with I 〉 2 o（I）.
A new metal-organic coordination complex [Zn（H2BPTC）（phen）2]n.3nH2O （BPTC = 3,3＇,4,4＇-benzophenone tetracarboxylate, phen = 1,10-phenanthroline） 1 has been obtained from hydrothermal reaction and characterized by elementaj analysis, IR, TG and single-crystal X-ray diffraction. In compound 1, the zinc cation is hexa-coordinated with two carboxylate oxygen atoms from one H2BPTC ligand and four nitrogen atoms from two different phen ligands, showing a slightly distorted octahedral geometry. Crystal data： C41H30N4O12Zn, Mr = 836.06, monoclinic, P21/c, a = 14.2714（9）, b = 16.9386（10）, c = 15.0151（9）A, β = 101.3420（10）^o, V= 3558.8（4）A3 Dc = 1.560 g/cm^3,μ（MoKa） = 0.766 mm^-1, F（000） = 1720, Z= 4, R = 0.0439 and wR = 0.1157 for 4123 observed reflections with I 〉 2 o（I）.
基金
The project was supported by the Education Office of Jilin Province (No. 0047)
