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Metal-free synthesis of amphiphilic functional polycarbonates

Metal-free synthesis of amphiphilic functional polycarbonates
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摘要 Amphiphilic block copolymers of poly(5-benzyloxy trimethylene carbonate) (PBTMC) and poly(ethylene glycol) (PEG) were synthesized through enzymatic polymerization using immobilized porcine pancreas lipase (IPPL). The obtained copolymers with different compositions were characterized by GPC and IH NMR. The copolymer composition was in agreement with the feed ratio. The molecular weight of the copolymers showed an increasing trend with the decrease of PEG contents. MiceUes of the copolymers were formed by dialysis procedure, and characterized by transmission electron microscopy (TEM). Amphiphilic block copolymers of poly(5-benzyloxy trimethylene carbonate) (PBTMC) and poly(ethylene glycol) (PEG) were synthesized through enzymatic polymerization using immobilized porcine pancreas lipase (IPPL). The obtained copolymers with different compositions were characterized by GPC and IH NMR. The copolymer composition was in agreement with the feed ratio. The molecular weight of the copolymers showed an increasing trend with the decrease of PEG contents. MiceUes of the copolymers were formed by dialysis procedure, and characterized by transmission electron microscopy (TEM).
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第12期1528-1530,共3页 中国化学快报(英文版)
关键词 Amphiphilic block copolymer Enzymatic polymerization POLYCARBONATE Amphiphilic block copolymer Enzymatic polymerization Polycarbonate
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