摘要
联苯甲酰双缩氨基脲硝酸钕水合物分子式为[Nd（C16H16N6O2）（NO3）3（H2O）]·H2O，Mr＝690．2，正交晶系，空间群为Fdd2，晶胞参数，利用2312个可观测衍射进行结构修正，最后R＝0.048。晶体中含有2个水分子，其中1个参加配位。3个硝酸根呈双齿配应；有机配体中有2个N原子和两个O原子参与配位，Nd的总配位数为11。
The crystal structure of biphenyl methylamide double semicarbazone neodymium nitrate has been determined by X-ray diffraction methed. Its crystal is orthorhombic, space group Fdd2, a The crystal structure was solved by direct methods and refined to observed reflections. The central Nd ion is ll-coordinated, by six oxygen atoms from three nitrate groups, two nitrogen atoms and two oxygen atoms from the neutral ligand, the eleventh is contributed by a water molecule.
基金
国家自然科学基金
