摘要
测定了化合物（Et4N）2[Ti（mp）3Na（MeOH）2（1）和（Et3NH）[Ni（mp）（mph）-（BU3P）]（2）的1H，13CNMR谱，对其谱线作了分析与归属。实验结果表明：化合物（1）在DMSO溶液中被解离成单核化合物（Ti（mp）3]2-，化合物（2）在DMSO溶液中仍保留原有固态分子结构。
1H, 13C NMR spectra of transition-metal compounds with O-mercaptophenol ligand (Et4N)2-[Ti(mp)3Na(MeOH)2]2(1)and (Et3NH) (Ni(mp) (mph) (Bu3P) (2) have been determined, ana-lyzed and assigned. The results indicate that compound (1) dissociates into two [Ti(mp)3]2- u-nits in DMSO solution while compound (2) is stable as the molecular structure remains the sameas in solid state.
关键词
邻巯基苯酚
NMR
钛
镍
配合物
nickel complex,titanium complex, o-mercaptophenol ligand, NMR
