摘要
本文用量子化学从头计算方法（ａｂｉｎｉｔｉｏ）研究了乙二醛在碱性条件下的Ｃａｎ－ｎｉｚａｒｏ重排反应，得到了该反应可行的微观机理。
Ab initio method in quantum chemistry is used to study the Cannizzaro rearrangement of glyoxal at presence of bases. Feasible reaction mechanism is obtained, which is in accordance with the experimental results by the isotopic trucing.
出处
《四川师范大学学报（自然科学版）》
CAS
CSCD
1997年第4期86-89,共4页
Journal of Sichuan Normal University（Natural Science）
