摘要
提出了油／水两相水解法精制六氯环三磷腈工艺。将4g粗六氯环三磷腈溶于30mL石油醚（90～120℃）中，按1：2（mL／mL）的油水比加入蒸馏水，温度60℃下剧烈搅拌8h，5℃水中结晶，精制六氯环三磷腈纯度达98．3％，收率76．1％。
A technology used to refine hexachlorocyclotriphosphazene with oil/water hydrolysis is put forward. We put 4 g crude hexachlorocyclotriphosphazene into 30 mL light petroleum（90～120 ℃）, then add distilled water to the system according to the oil/water ration 1 ： 2（mL/mL ） and stir the liquid under the temperature 60℃ about 8 hours. The refined hexachlorocyclotriphosphazene is crystallized at 5 ℃ in water, and it purity is up to 98.2%. The recycle yield is 73%.
出处
《长春工业大学学报》
CAS
2007年第4期438-440,共3页
Journal of Changchun University of Technology
基金
吉林省教育厅科技基金资助项目(200245)
关键词
六氯环三磷腈
油/水两相水解法
精制
hexachlorocyclotriphosphazene
oil/water hydrolysis
refine.
