光学活性松干蚧性信息素C-8～C-13片断的合成

Synthesis of the C - 8-C - 13 fragment of the natural occuring sex pheromone of Matsucoccus matsumurae Japanese pine bast scale

本文报道了从(S)-香茅醇合成化合物(2R)-3,5-dimethyl-hexan-1-ol(9),即光学活性日本松干蚧性信息素C-8～C-13片断,共经九步反应,总产率为57%。

(3R)-3, 5-dimethyl- hexan - 1 - ol(9), the C-8-C- 13 fragment of the sex pheromone of Japanese pine bast scale, Matsucoccus matsumurae was synthesized from ( S ) -citronellol in 57% total yield over nine steps.