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C_(60)离子束撞击固体表面的坍塌沉积(Ⅰ)共焦显微拉曼光谱研究 被引量:2

Collapsed Deposition of Accelerated C_(60) Beam on Solid Surfaces (Ⅰ) Confocal Raman Microscopic Studies
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摘要 Raman spectroscopy was applied to characterize the species deposited from the mass-selected C60 ion beam which was accelerated to 900 eV. The substrates for the deposition were (0001) surface of highly oriented pyrolitic graphite and (111) surface of gold crystal. The species do not echibit the Raman scattering features of buckminsterfullerene, but displays peaks at 1585 and 1332 cm-1 instead. The former peak is the chararteristic hanan peak of hexagonal graphite,and the latter can be attributed to the amorphous carbon in sp3 hybridization. The result reveals that C60 was collapsed to form a new phase when it collides on the solid surface. Raman spectroscopy was applied to characterize the species deposited from the mass-selected C60 ion beam which was accelerated to 900 eV. The substrates for the deposition were (0001) surface of highly oriented pyrolitic graphite and (111) surface of gold crystal. The species do not echibit the Raman scattering features of buckminsterfullerene, but displays peaks at 1585 and 1332 cm-1 instead. The former peak is the chararteristic hanan peak of hexagonal graphite,and the latter can be attributed to the amorphous carbon in sp3 hybridization. The result reveals that C60 was collapsed to form a new phase when it collides on the solid surface.
机构地区 厦门大学化学系
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1997年第6期481-483,共3页 Acta Physico-Chimica Sinica
基金 国家自然科学基金 国家教委资助
关键词 坍塌沉积 共焦显微 拉曼光谱 碳60 离子束 结构 C_(60), Raman spectroscopy, Collapse, Deposition
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  • 1Huang R B,Int J Mass Spect Ion Process,1995年,55卷,105页

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