摘要
在VPO催化剂中添加Pr,用XRD、LRS、XPS、ESR和31P固体核磁共报考察了催化剂的相组成和机的氧化态,用NH3-TPD和吡啶吸附原位红外光谱表征了催化剂表面的酸量.将催化剂应用于正丁烷选择氧化生成顺酐醉的反应中。实验结果表明,当Pr/V(原子比)=0.05时,活性相(VO)2P2O7的量增加,表面酸性增强,正丁烷转化率和生成顺酐的选择性都有所很高,而Pr/V>0.10时,(VO)2P2O7的量减小,表面酸性降低。
Influence of doping Pr on the characteristics of VPO catalyst was investigated by means of XRD, XPS, ESR, 31P NMR, NH3-TPD and IR techniques. The catalysts were used in the selective oxidation of n-butane to maleic anhydride. Experimental results showed that,when Pr/V(atomic ratio)=0.05,the amount of (VO)2P2O7 was increased and the surface acidity was enhanced, and the conversion of n-butane and the selectivity to maleic anhydride reached a maximum value respectively. While Pr/V>0.10, the amount of(VO)2P2O7 and surface acidity were decreased and the activity of catalysts was reduccd.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1997年第6期548-553,共6页
Acta Physico-Chimica Sinica
基金
河北省自然科学基金
北京中关村地区测试基金
关键词
VPO催化剂
正丁烷
顺酐
氧化
镨
Praseodymium,VPO catalyst, n-Bntane, Maleic anhydride