期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

锂离子电池正极材料LiFePO_4的研究进展

Research Development of LiFePO_4 as Cathode Material of Li-ion Battery
下载PDF
导出
摘要 LiFePO_4因具有高的比容量、良好的循环性、环境友好等特点,成为目前最受关注的锂离子电池正极材料。概述了LiFePO_4的结构和电化学性能,介绍了LiFePO_4主要的几种制备方法,包括固相法、水热法、微波法。同时阐述了提高LiFePO_4电化学性能所做的改性研究,并对该材料的发展方向进行了展望。 LiFePO4 has become an attractive cathode material for Li-ion battery since it has hight specific capacity,good cycle capability and environmentalbenifits. The structure and electrochemical performance of LiFePO4 are summarized in this paper. The main preparing methods of the material are analyzed, including solid-state reaction, hy- drothermal synthesis and microwave synthesis. At the same time, the related modification research on enhancing the capability of LiFePO4 is introduced and the further development trend of the material is expected.
作者 张亚利 高立军 吁霁
机构地区 南昌大学理学院化学系
出处 《材料导报》 EI CAS CSCD 北大核心 2007年第F11期303-305,312,共4页 Materials Reports
基金 国家自然科学基金(20663005)
关键词 正极材料 LIFEPO4 电化学性能 cathode materials, LiFePO4, electrochemical performance
分类号 TM912.9 [电气工程—电力电子与电力传动]
  • 相关文献

参考文献32

  • 1Arascon J M, Armand M. Issues and challenges facing rechargeable lithium batteries. Nature, 2001,144(15) :360.
  • 2Padhi A K, Najundaswamy K S, Goodenough J B. Phosphoolivines as positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc, 1997,144 (4) : 1188.
  • 3MacNeil D D, Lu Zhonghua,Chen Zhaohui, et al. A comparison of the electrode/electrolyte reaction at elevated temperatures for various Li-ion battery cathodes. J Power Sources, 2002,108:8.
  • 4Takahashi M, Tobishima S, Takei K, et al. Reaction behavior of LiFePO4 as a cathode material for rechargeable lithium batteries. Solid State Ionics, 2002,148(3-4) : 283.
  • 5Yang S F, Song Y N, Zavalij P Y, et al. Reactivity, stability and electrochemical behavior of lithium iron phosphates. Electrochem Commun, 2002,4(3) : 239.
  • 6Yamada A, Chng S C, Hinokuma K. Optmized LiFePO4 for lithium battery cathodes. J Electrochem Soc, 2001,148(3): A224.
  • 7Shigeto O, Shoichiro S, Monato E, et al. Cathode properties of phosphor-olivine LiMPO4 for lithium secondary batteries. J Power Sources,2001,97 98 : 430.
  • 8Padhi A K, Nanjundaswam K S, Masquelier C, et al. Effect of structrue on the Fe^3+/Fe^2+ redox couple in iron phosphates. J Electrochem Soc, 1997,144(5) : 1609.
  • 9Andersson A S, Kalska B, Haggstrom L, et al. Lithium extraction/insertion in LiFePO4: an X ray diffraction and mossbauer spectroscopy study. Solid State Ionics, 2000,130 (1):41.
  • 10Thuckeray M. An unexpected conductor. Nature Mater, 2002,2:81.

二级参考文献28

  • 1Padhi A K, Nanjundaswamy K S, Goodenough J B. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries[J ]. J Electrochem Soc, 1997, 144(4) : 1188 - 1194.
  • 2Atsuo Y, Sai-Cheong C, Hinokuma K. Optimized LiFePO4 for lithium battery cathodes[J] .J Electrochem Soc, 2001, 148(3) :224 - 229.
  • 3Shoufeng Y, Yanning S, Peter Y, et al. Reactivity, stability and electrochemical behavior of lithium iron phosphates [ J ]. Electrochem Comm, 2002, 4(3) : 239 - 244.
  • 4Masaya T, Shinichi T, Koji T, et al. Characterization of LiFePO4 as the cathode material for rechargeable lithium batteries [ J ]. J Power Sources, 2001, 97 - 98:508 - 511.
  • 5Zhao H C, Dahn J D. Reducing carbon in LiFePO4/C composite electrodes to maximize specific energy, volumetric energy and tap density[J] .J Electrochem Soc, 2002, 149(9) : 1184 - 1189.
  • 6Croce F, Epifanio A D, Hassoun J, et al. A novel concept for the synthesis of an improved LiFePO4 lithium battery cathode[ J ]. Electrochemical and Solid-State Letters, 2002, 5 (3) : 47 - 50.
  • 7Yamada A, Chung S C, Hinokuma K. Optimized LiFePO4 for lithium battery cathodes [J ]. J Electrochem Soc, 2001, 148 ( 3 ) : A 224 -A 229.
  • 8Huang H, Yin S C, Naz I. F. Approaching theoretical capacity of LiFePO4 at room temperature at high rates[J ]. Electrochemical and Solid-State Letters. 2001,4(10): AI70 - A172.
  • 9Prosini P P, Zane D, Pasquali M. Improved electrochemical performance of a LiFePO4-based composite cathode[J]. Electrochimica Acta, 2001, 46(23):3 517 - 3 523.
  • 10Croce F, D' Epifanio A, Hassoun J, et al. A novel concept for the synthesis of an improved LiFePO4 lithium battery cathode [J ].Electrochemical and Solid-State Letters, 2002, 5 (3) : A47 - AS0.

共引文献87

材料导报
2007年 第F11期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部