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硝基苯气相加氢催化剂Cu/SiO_2的改性研究 被引量:15

Effect of Cr and Mo on Vapor Phase Hydrogenation Catalysts Cu/SiO 2 for Nitrobenzene
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摘要 硝基苯气相加氢催化剂Cu/SiO2的改性研究方向明*李凤仪夏克坚秦中(南昌大学现代应用化学研究所南昌330047)(江西OAI-中德联合研究院南昌)关键词硝基苯,苯胺,加氢催化剂1996-08-02收稿,1996-11-18修回苯胺是染料、医药、农药... Cu/SiO 2 catalysts modified by Cr 2O 3 and MoO 3 have been characterized with a continuous fixed bed reactor. The influence of Cr 2O 3 and MoO 3 on the surface properties and active site of catalysts has also been studied with TPR, XPS and XRD. The results show that catalytic properties of catalysts modified by Cr and Mo are improved remarkably and Cr 2O 3 and MoO 3 in the catalysts have the property of donating electrons towards Cu particles. Adding proper amounts of Cr, Mo to catalysts can increase the dispersity of Cu particles and the stability of catalysts.
出处 《应用化学》 CAS CSCD 北大核心 1997年第2期57-59,共3页 Chinese Journal of Applied Chemistry
关键词 硝基苯 苯胺 加氢催化剂 二氧化硅 nitrobenzene,phenylamine,hydrogenation catalyst
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  • 1陆伟杰,伏义路,许存义,黄志刚,吴建新,范立.负载的钼催化剂表面结构的研究[J].Chinese Journal of Chemical Physics,1989,2(3):222-232. 被引量:6
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  • 3伏义路,第五届全国催化学术报告会议摘要集,1990年

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