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Lewis酸促进无配体钯盐催化的Suzuki反应研究 被引量：3

Rate enhancement in ligand-free palladium catalyzed Suzuki reaction by Lewis acid promoters
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摘要 研究了Lewis酸在Suzuki反应中的促进作用,考察了Lewis酸、溶剂及碱性试剂对目的产物收率的影响,并优化了反应条件。结果表明,FeCl3·6H2O对Suzuki反应有明显的助催化作用。当采用乙醇作溶剂,K2CO3作碱性试剂,在溴苯和苯硼酸反应体系中加入FeCl3·6H2O后,联苯产率由56%增加至88%。 The rate enhancement in homogeneous Suzuki reaction by Lewis acid has been investigated. The effects of Lewis acid, solvent and base on the yields of object product have been also studied, and the reaction conditions are optimized. Significant enhancement has been achieved when a catalytic amount of FeCI3 ＂6H20 is used. The yields of biphenyl increased from 56 % to 88 % in the presence of ethanol as solvent,K2CO3 as base and FeCl3·6H2O as catalytic promoter.
作者 范国枝 胡志军 王紫兰
机构地区 武汉工业学院化学与环境工程系
出处 《现代化工》 EI CAS CSCD 北大核心 2008年第1期41-43,共3页 Modern Chemical Industry
基金 湖北省自然科学基金资助项目(2007ABA369)
关键词 SUZUKI偶联反应 LEWIS酸 促进 催化 Suzuki coupling reaction Lewis acid enhancement catalysis
分类号 O626.12 [理学—有机化学] O623.662 [理学—有机化学]
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参考文献19

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同被引文献28

  • 1周少林,徐利文,夏春谷,李经纬,李福伟.Suzuki偶联反应的最新研究进展[J].有机化学,2004,24(12):1501-1512. 被引量：31
  • 2龚军芳,刘广宇,朱玉,杜晨霞,宋毛平,吴养洁.环钯化二茂铁亚胺-三苯基膦配合物的合成、表征及催化Suzuki反应研究[J].高等学校化学学报,2006,27(7):1266-1271. 被引量：17
  • 3张峰,张歆.Pt／介孔TiO_2-SiO_2的制备、表征及光催化性能研究[J].无机材料学报,2006,21(5):1268-1272. 被引量：16
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  • 6GONZALEZ-ARELLANO C, CORMA A, IGLESIAS M, et al. Pd (II)-Schiff base complexes heterogenised on MCM-41 and delaminated zeolites as efficient and recyclable catalysts for the Heck reaction[J]. Advanced Synthesis Catalysis ,2004,346( 13/14/15 ) : 1758-1764.
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现代化工
2008年 第1期

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