期刊文献+

多面体低聚倍半硅氧烷(POSS)杂化材料 被引量:10

Hybrid Materials Based on Polyhedral Oligomeric Silsesquioxanes
下载PDF
导出
摘要 POSS作为一种特殊的有机-无机杂化材料,在结构上具有很强的可设计性,为新材料的研究提供了极大的便利,在近几年的研究中备受人们关注。介绍了POSS合成的研究进展,重点综述了近几年POSS杂化材料在光电材料、聚合物阻燃和材料表面改性等领域的应用。指出基于POSS的杂化材料发展前景广阔,在未来材料科学发展中将发挥重要作用。 Polyhedral oligomeric silsesquioxane (POSS) as a special family of organic-inorganic hybrid material has attracted considerable interest in the last few years. The structures of these hybrid materials can be designed easily according to the requirements, which provides great convenience to the research of new materials. In this paper, the synthesis methods of POSS are introduced, and the applications of POSS-based hybrid materials in the fields such as photoelectric materials, flame retardance of polymer and surface modification of the materials are reviewed. It is pointed out that the hybrid materials based on POSS will be widely used and play an important role in the development of material science in the future.
出处 《材料导报》 CSCD 北大核心 2008年第2期9-12,30,共5页 Materials Reports
基金 江苏省高技术研究项目(BG2007047)资助
关键词 POSS 杂化材料 光电材料 聚合物阻燃 表面改性 polyhedral oligomeric silsesquioxane (POSS), hybrid materials, photoelectric materials, flame retardance of polymer, surface modification
  • 相关文献

参考文献39

  • 1Mauritz K A, Mountz D A, Reuschle D A, et al. Self-assembled organic/inorganic hybrids as membrane materials. Electrochimica Acta, 2004,50 : 562
  • 2Voronkov M G, Lavrent'yev V I. Polyhedral oligosilsesquioxanes and their homo derivatives. Top Curr Chem, 1982, 102:199
  • 3Li G Z, Wang L C, Ni H L, et al. Polyhedral oligomeric silsesquioxane (POSS) polymers and copolymers: A review. J Inorg Organometallic Polym, 2001,11(3) : 123
  • 4Toepfer O, Neumann D, Choudhury N R, et al. Organicinorganic poly(methyl methacrylate-) hybrids with confined polyhedral oligosilsesquioxane macromonomers. Chem Mater, 2005,17 : 1027
  • 5Phillips S H, Haddad T S, Tomczak S J. Developments in nanoscience:polyhedral oligomeric silsesquioxane (POSS)- polymers. Current Opinion in Solid State and Materials Science, 2004,8(1) :21
  • 6Sprung M M, Guenther F O. The partial hydrolysis of ethyltriethoxysilane. J Am Chem Soc, 1955,77(15) : 3996
  • 7Brown J F. The polycondensation of phenylsilanetriol. J Am Chem Soc, 1965,87(19) : 4317
  • 8Tamaki R, Tanaka Y, Asuncion M Z, et al. Octa(aminophenyl) silsesquioxane as a nanoconstruction site. J Am Chem Soc, 2001, 123: 12416
  • 9Feher F J , Wyndham K D. Amine and ester-substituted silsesquioxanes. Chem Commum, 1998,3 : 323
  • 10Braunstein P, Galsworthy J R, Hendan B J, et al. Reactions of thiol-functionalized silsesquioxanes with metal car- Donyl clusters: syntheses and characterization of [Si8O12 (Pr^n)7{(μ2-SC4H6)-M3(μ-H)(CO)10}] (M=Ru, Os; Pr^n = C3H7), [Si8O12-(Pr^n)6 {(μ2-SC3H6) Ru3 (μ-H) (CO)10 }2] and [Si8 O12-(C3H6SH)x{ (μ2-SC3H6)Ru3(μ-H) (CO)10}8-x] (x=6, 0). J Organomet Chem, 1998, 551: 125

二级参考文献15

  • 1王庆国,张军,张峰.锥形量热仪的工作原理及应用[J].现代科学仪器,2003,20(6):36-39. 被引量:104
  • 2Iji,Masatashi,Serizawa,Shin.The relationship between thermal degradation behavior of polymer and the fire retardancy of polymer/clay nanocomposites[J].Purasuchikksu Eji,1998,44 (2):146-49.
  • 3Waddon A J.Coughlin E B.Crystal structure of polyhedral oligomeric silsequioxane (POSS) nano-materials:A study by X-ray diffraction and electron microscopy[J].Chemistry of Materials,2003,15(24):4 555-4 561.
  • 4Ryo Tamaki,Jiwon Choi,Richard M Laine.A polyimide nanocomposite from octa(aminophenyl)silsesquioxane[J].Chemistry of Materials,2003,15:793-797.
  • 5Jiwon Choi,Ryo Tamaki.Seung Gyoo Kim,et al.Organic/inorganic imide nanocomposites from aminophenylsilsesquioxanes[J].Chemistry of Materials,2003,15:3 365-3 375.
  • 6Laine R M,Choi J,Lee I.Organic-inorganic nanocomposites with completely defined interfacial interactions[J].Advanced Materials,2001,13:800-803.
  • 7Choi J,Harcup J,Yee A F,et al.Organic/inorganic hybrid composites from cubic silsesquioxanes[J].Journal of the American Chemical Society,2001,123:11 420-11 430.
  • 8Ryo Tamaki,Yasuyuki Tanaka,Michael Z,et al.Octa(aminophenyl)silsesquioxane as a nanoconstruction site[J].Journal of the American Chemical Society,2001,123:12 416-12 417.
  • 9Babrauskas V,Grayson S J.Heat Release in Fires[M].London:Elsevier,1992:461-478.
  • 10Babrauskas V.Bench Scale Methods for Prediction of Full Scale Fire Behavior of Furnishings and Wall linings[R].Boston:Society of Fire Protection Engineers,1984.

共引文献21

同被引文献165

引证文献10

二级引证文献31

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部