两相催化──均相催化多相化新进展

Two Phase CatalysisRecent Advances in the Heterogenization of Homogeneous Catalysis

评述了水溶性膦配体和两相催化研究领域的进展，探讨了固载水相催化、温控相转移催化和氟两相体系等新型两相催化体系。两相催化在烯烃的氢甲酰化反应、不饱和化合物的加氢反应以及其它有机反应中获得了广泛的应用。

Recent developments in the chemistry of water soluble phosphines and two phase catalysis are discussed, including several novel two phase catalytic systems that are supported aqueous phase catalysis, thermoregulated phase transfer catalysis, and fluorous biphase system. Numerous applications of two phase catalysis to hydroformylation, hydrogenation and other organic reactions are also described.