期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

二氨基偶氮二氧化呋咱的合成及表征 被引量：2

Synthesis and Characterization of 3,3′-Diamino-4,4′-azofuroxan
下载PDF
导出
摘要 以乙酰乙酸乙酯为原材料制备了氧化呋咱类关键中间体4-氨基-3-叠氮羰基氧化呋咱,以此为前体合成了二氨基偶氮二氧化呋咱(DAAFO)。采用元素分析、红外、质谱和热分析等方法对上述物质进行了表征。结果表明,4-氨基-3-叠氮羰基氧化呋咱感度略高于二氨基呋咱、HMX;二氨基偶氮二氧化呋咱放热分解峰温为208.17℃,低于二氨基偶氮二呋咱和二氨基氧化偶氮二呋咱。 3,3 ＇-Diamino-4,4＇-azofuroxan （DAAFO） was synthesized by a two-step process, with 4-amino-3-azidocarbonylfuroxan as precursor which was synthesized by a three-step process with ethyl acetoacetate as starting material. The DAAFO and mediate products were characterized by DSC-TG, elemental analysis,IR and MS. And the sensitivity and DSC analysis of DAAFO were carried out and compared. The results show that 4-amino-3-azidocarbonylfuroxan is more sensitive than diaminofurazan and HMX. The peak decomposition temperature of DAAFO is 208. 17 ℃ , lower than that of 3,3＇-diamino-4,4＇-azofurazan （DAAF） and 3,3＇-diamino-4,4＇-azoxyfurazan （ DAOAF）.
作者 雷晴 何金选 郭滢媛 曹一林
机构地区 中国航天科技集团公司四院四十二所
出处 《含能材料》 EI CAS CSCD 2008年第1期53-55,共3页 Chinese Journal of Energetic Materials
基金 国家重大安全基础研究项目(973)61337-01
关键词 有机化学 4-氨基-3-叠氮羰基氧化呋咱 二氨基偶氮二氧化呋咱(DAAFO) 合成 organic chemistry 4-amino-3-azidocarbonylfuroxan 3,3 ＇-diamino-4,4 ＇-azofuroxan （ DAAFO ） synthesis
分类号 O626 [理学—有机化学]
  • 相关文献

参考文献5

  • 1Gunasekaran A ,Jayachandran T,Boyer J H,et al. A convenient synthesis of diaminoglyoxime and diaminofurazan : useful precusors for the synthesis of high density energetic materials [J]. J Heterocyclic Chem, 1995,32:1405.
  • 2Kulikov A S, Ovchinnilov I V. Synthesis of furoxan derivatives based on 4-aminofuroxan-3-carboxylic acid azide[J]. Russian Chemical Bulletin, 2003,52(8) : 1822-1828.
  • 3Nina N Makhova, Alexander N Blinnikov. 4-Amino-3-azidocarbonylfuroxan as an universal syntol for the synthesis of energetic compounds of the furoxan series[C]//30th Int. Annu. Conf. of ICT. 1999.
  • 4Ovchinnilov I V, Kulikov A S. The Curtius rearrangement of azidocarbonylfuroxan: Some peculiarities and the synthesis of aminofuroxans [J]. Mendeleev Commun,1995,(2):58-60.
  • 5Lobbecke S, Schuppler H, Schweikert W. Thermal properties of different substituted energetic furoxans[C]//33th Int. Annu. Conf.of ICT. 2002.

同被引文献20

  • 1Kulikov A S. Synthesis of furoxan derivatives based on 4-aminofuroxan-3 earboxylic acid azide [J]. Russian Chemical Bulletin, International Edition, 2003,52 (8) 1822- 1828.
  • 2Makhova N N, Blinnikov A N,Oveminnikov I V,et al. 4-Amino-3-azidocarbonylfuroxan as a universal synton for the synthesis of energetic compounds of the furoxan series[C]//30th Inter Annu Conf of ICT. Karlsruhe: ICT,1999,58: 1-10.
  • 3Ovchinnikov I V, Blinikov A N, Makhova N N,et al. The curtius rearrangement of azidocarbonylfuroxans: some peculiarities and the synthesis of aminofuroxans [J]. Mendeleev Communications, 1995,5 ( 2 ), 58-60.
  • 4Sikder A K,Sikder N. A review of advanced high per formance, insensitive and thermally stable energetic materials emerging for military and space applications[J]. Journal of Hazardous Materials,2004,112: 1-15.
  • 5Orakauskas V,Guest A M. Dinitromethane[J]. The Jour nal of Organic Chemistry, 1978,43(18) : 3485-3488.
  • 6郭涛,刘敏,姜俊,等.3,3'-二氨基4,4'-偶氮氧化呋咱的合成方法:CN,103086997A[P].2013.
  • 7Kulikov A S, Ovchinnikov I V, Molotov S I, et al. Synthesis of furoxan derivatives based on 4-aminofu- roxan-3-carboxylie acid azid [J].Russian Chemical Bulletin, 2003, 52(8): 1822-1828.
  • 8Epishina M A, Finogenov A O, Kulikov A S, et al. Synthesis and nitration of 3 R-4-(2, 2, 2-trinitroethyl) aminofuroxans[J]. Russian Chemical Bulletin, 2012, 61(8) : 1575-1581.
  • 9Finogenov A O, Kulikov A S, Epishina M A, et al. The first synthesis of furoxan and 1,3,4-oxadiazole ring ensembles[J]. Journal of Heterocyclic Chemis- try, 2013, 50(1): 135-140.
  • 10Shimizu T, Hayashi Y, Teramura K, et al. A new synthetic method for alkyl carbonocyanidate N-oxides [J]. Bulletin of the Chemical Society of Japan, 1985, 58(9) : 2519-2522.

引证文献2

二级引证文献11

含能材料
2008年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部