丙烯齐聚非均相催化剂的研究进展

HETEROGENEOUS CATALYSTS FOR PROPYLENE OLIGOMERIZATION

综述了近10年来丙烯齐聚非均相催化剂的研究进展,讨论了催化剂载体的种类、结构和性质,金属阳离子种类、价态和迁移规律等对丙烯齐聚反应的影响,并对催化剂活性中心、反应中间体的形成和催化反应机理进行了深入的论述。指出丙烯齐聚非均相催化剂存在的主要问题活性中心易流失,提出了丙烯齐聚非均相催化剂的研究和开发应以能够稳定活性中心的载体和添加剂为重点。

Advances in heterogeneous catalysts for propylene oligomerization in the last ten years was reviewed. The kinds, structure and properties of carriers, the kinds, valent state and migration mechanism of metal cations were discussed. Active sites of the catalysts, formation of intermediates in the reaction and catalysis mechanism were also discussed. The problem with the heterogeneous catalysts for propylene oligomerization was the loss of the active sites in the reaction. Research and development of new carriers and additives stabilizing active sites were emphasized, which was the focus of the research for heterogeneous catalysts.