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Synthesis and characterization of novel poly(aryl ether sulfone ketone)s containing phthalazinone and biphenyl moieties 被引量:3

Synthesis and characterization of novel poly(aryl ether sulfone ketone)s containing phthalazinone and biphenyl moieties
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摘要 A novel series of poly(aryl ether sulfone ketone)s (PPESKs) containing phthalazinone and biphenyl moieties were prepared by two-step nucleophilic polycondensation reaction. The ^-Mw values of these copolymers were between 38,330 and 67,900. The glass transition temperatures (Tg) and 5% decomposition temperatures were ranged in 253-269 ℃ and 488-500 ℃, respectively, The structures of these copolymers were confirmed by FT-IR and ^1H NMR. Moreover, all the resultant copolymers were amorphous determined by wide angle X-ray diffraction (WAXD). A novel series of poly(aryl ether sulfone ketone)s (PPESKs) containing phthalazinone and biphenyl moieties were prepared by two-step nucleophilic polycondensation reaction. The ^-Mw values of these copolymers were between 38,330 and 67,900. The glass transition temperatures (Tg) and 5% decomposition temperatures were ranged in 253-269 ℃ and 488-500 ℃, respectively, The structures of these copolymers were confirmed by FT-IR and ^1H NMR. Moreover, all the resultant copolymers were amorphous determined by wide angle X-ray diffraction (WAXD).
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第2期227-229,共3页 中国化学快报(英文版)
关键词 Poly(aryl ether sulfone ketone) PHTHALAZINONE BIPHENYL Thermal property Solubility Poly(aryl ether sulfone ketone) Phthalazinone Biphenyl Thermal property Solubility
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  • 1[1]X.G.Jian,Y.Z.Meng,Chinese Patent 93109179.9 (1993).
  • 2[2]X.G.Jian,G.X.Liao,Chin.Plast.16 (2002)11.
  • 3[3]Y.Z.Meng,A.S.Hay,X.G.Jian,J.Appl.Polym.Sci.66 (1997)1425.
  • 4[4]IR absorption spectra were recorded by transmission method with a Thermo Nicolet Nexus 470 Fourier transform infrared (FFIR)spectrometer (film,cm-1):1325 (-SO2),1669 (C=O),1242 (C-O-C);1H NMR (400 MHz,CDCl3,δ (ppm)):8.36-8.96 (lI-I),7.64-8.36 (15H),7.48-7.64(4H),7.3 (CDCl3),6.50-7.48 (18H),2.50-4.50 (4H),0.6-2.5 (10H).

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