摘要
研究了ZrC l4催化的苯乙烯与取代芳香胺的氢胺化反应,讨论了该反应过程中催化剂的用量,反应温度,以及含不同取代基的芳胺对产率的影响。利用该方法合成了5种取代的N-(1-苯基乙基)苯胺,其结构经1H NMR,13C NMR和MS表征。
ZrCl4-catalyzed hydroamination reactions of styrene were investigated. Five N-（ 1-phenylethyl） anilines were synthesized via reactions of styrene with different substituted anilines using ZrCl4 as a catalyst. The structures were characterized by ^1 H NMR, ^13 C NMR and MS. The effects of the reaction temperature and the catalyst loadings on the hydroamination reactions were also discussed.
出处
《合成化学》
CAS
CSCD
2008年第1期112-114,共3页
Chinese Journal of Synthetic Chemistry
基金
江苏省自然科学基金资助项目(BK2005030)
教育部留学回国人员基金资助项目(K5109609)
关键词
氢胺化反应
ZrCl4
催化
合成
hydroamination
zirconium tetrachloride
catalysis
synthesis
