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磷酸铁锂正极材料的合成与表征技术 被引量:14

Synthesis and characterization technique of LiFePO_4 cathode material
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摘要 橄榄石型磷酸铁锂正极材料具有原料来源丰富、价廉、无毒、环境友好、理论容量高、热稳定性和循环性能好等特点,有望成为新一代锂离子电池正极材料。综述了高温固相反应法、溶胶-凝胶法、微波合成法、水热合成法和共沉淀法制备磷酸铁锂的方法。并详细说明了磷酸铁锂的红外光谱、扫描电镜、X射线衍射和电化学性能研究等表征技术。 The olivine lithium iron phosphate ( LiFePO4 ) has the potential to be a new commercial cathode material for lithium ion battery due to its abundant resources, low cost, non- toxicity, environmental benignancy, high theoretical capacity,good thermal stability and excellent cycling performance. The synthetic methods of LiFePO4, such as high temperature solid state reaction method, sol -gel method, microwave radiation method, hydrothermal method and co- precipitation method, were summarized. The characterization techniques of LiFePO4, such as IR, SEM, XRD and electrochemical property analysis etc. were introduced in detail.
出处 《无机盐工业》 CAS 北大核心 2008年第2期13-16,共4页 Inorganic Chemicals Industry
关键词 磷酸铁锂 正极材料 制备 表征 lithium iron phosphate cathode material preparation characterization
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参考文献21

  • 1Padhi A K, Nanjundaswamy K S, Goodenough J B. Phospho - o - livines as positive - electrode materials for rechargeable lithium batteries[ J]. J. Electrochem. Soc., 1997,144(4) : 1188 - 1194.
  • 2Masaya Takahashi, Shinichi Tobishima, Koji Takei, et al. Reaction behavior of LiFePO4 as the cathode materials for rechargeable lithium batteries [ J ]. Solid State lonics,2002,148 (3 - 4 ) :283 - 289.
  • 3Pier Paolo Prosini, Marda Lisi, Daniela Zane, et al. Determination of the chemical diffusion coefficient of lithium in LiFePO4 [ J ]. Solid State Ionics, 2002,148:3517 - 3523.
  • 4李于华,金头男,杨丽娟,肖卫强.蔗糖的添加对磷酸亚铁锂形态与性能的影响[J].电源技术,2006,30(11):914-916. 被引量:10
  • 5刘恒,孙红刚,周大利,张萍,尹光福.改进的固相法制备磷酸铁锂电池材料[J].四川大学学报(工程科学版),2004,36(4):74-77. 被引量:36
  • 6Scroce F,Epifanio A D.A novel concept for the synthesis of an improved LiFePO4 lithium battery cathode [ J ]. Electrochem Solid - State Lett. ,2002,5 ( 3 ) : A47 - A50.
  • 7Xu Zhihui,Xu Liang,Lai Qiongyu,et al. A PEG assisted sol - gel synthesis of LiFePO4 as cathodic material for lithium ion cell [ J ]. Materials Research Bulletin, 2007,42 : 883 - 891.
  • 8Liu Xiaohong, Wang Jinqing, Zhang Junyan, et al. Fabrication and characterization of LiFePO4 nanotubes by a sol - gel - AAO template process[ J ]. Chinese Journal of Chemleal Physics, 2006,19 (6) :530 -534.
  • 9王小建,任俊霞,李宇展,魏进平,高学平,阎杰.微波法制备掺碳LiFePO_4正极材料[J].无机化学学报,2005,21(2):249-252. 被引量:18
  • 10Song Minsang, Kang Yongmook, Kim Jinho Kim, et al. Simple and fast synthesis of LiFePO4 - C composite for lithium rechargeable batteries by ball - milling and microwave heating [ J ]. Journal of Power Source,2007,66 : 260 - 265.

二级参考文献79

  • 1戴曦,唐红辉,杨平,张传福.LiFePO_4正极材料的研究进展[J].材料导报,2005,19(8):69-71. 被引量:15
  • 2王晓琼,李新海,王志兴,郭华军,张宝,张云河.LiFePO_4掺镍的改性研究[J].电池,2005,35(5):371-373. 被引量:13
  • 3雷敏,应皆荣,姜长印,万春荣.高密度球形LiFePO_4的合成及性能[J].电源技术,2006,30(1):11-13. 被引量:45
  • 4[1]Ravet N, Chouninard Y, Magnan J F, et al. Electroactivity of natural and synthetic triphylite [J].J Power Sources,2001,97-98:503~507.
  • 5[2]Yamada A, Chung S C, Hinokuma K. Optimized LiFePO4 for lithium battery cathodes[J].J Electrochem Soc,2001,148(3):A224~A229.
  • 6[3]Croce,a F, Epifanio A D, Hassoun J, et al. A novel concept for the synthesis of an improved LiFePO4 Lithium Battery Cathode[J].Electrochemical and Solid-State Letters,2002,5(3):A47~A50.
  • 7[4]Guo Z P, Liu H, Bewlay S, et al. Fine-particle Li0.98Mg0.02FePO4 synthesized by a novel modified solid-state reaction[C].The 204th Electrochemical Society Meeting,Orlando,Florida,Oct.2003.12~17.
  • 8[5]Padhi A K, Nanjundawamy K S, et al. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries[J].J Electrochem Soc,1997,144:1188~1192.
  • 9[6]Masaya Takahashi, Shinichi Tobishima, et al.Characterization of LiFePO4 as cathode material for rechargeable lithium battery[J].J Power Sources,2001,97-98:508~511.
  • 10[8]Chung S Y, Bloking J T, Chiang Y M, Electronically conductive phospho-olivines as lithium storage electrodes[J].Nature Materials,2002,123:1~6.

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