自组装和分散可逆的碳纳米管圆片(英文)

Self-organized and reversibly dispersible pellets of multi-walled carbon nanotubes

通过加热碳纳米管和强酸的混合物,使碳纳米管的憎水表面发生氧化。加热含经处理的碳纳米管的悬浮液,使之脱水,得到自组装的碳纳米管圆片,该圆片可直接分散。扫描电镜图显示该圆片由局部规则排列的碳纳米管构成;红外光谱和光电子谱分析表明在化学处理过程中,碳纳米管的表面产生了含氧官能团;虽然拉曼谱测出处理过程增加了缺陷,但是X射线衍射结果表明碳纳米管类似石墨的层状结构得到保留;同时研究了经处理的碳纳米管的热稳定性。这种自组装且可分散的碳纳米管圆片为研究碳纳米管结构材料和碳纳米管复合材料提供了有效途径。

Hydrophobic surfaces of multi-walled carbon nanotubes （CNTs） were oxidized by boiling a mixture of CNTs and concentrated acid. A self-organized pellet which can be reversibly dispersed was produced by dehydrating the oxidized CNT solution. Scanning electron microscope pictures showed that the pellet consisted of highly aligned nanotubes. Fourier transformation infrared and X-ray photoelectron spectroscopy indicated that oxygen-containing surface groups were introduced during the acid oxidation. Although an increased number of defects was shown by Raman spectroscopy, X-ray diffraction indicated that graphene layer organization remained after treatment. Thermal stability of treated CNTs was investigated and comparisons between pristine, treated, and heated CNTs were made. This well-packed and soluble pellets can provide ideal samples to study bulk CNT nanostructured materials and CNT composites.