摘要
详细讨论了樟脑磺酸掺杂的聚苯胺的溶解性及成膜性,讨论了具有较高电导率的聚苯胺所应有的特征和影响电导率的因素,制备出高强度、高电导的聚苯胺膜,并研究了其性质。
olubility and properties of polyaniline doped by camphor sulfonic acid(PAnCSA) was studied. The polyaniline film cast from mcresol chloroform solution has much high conductivity and strength which are about 200 ̄400 S cm and 30 MPa, respectively. PAnCSA film fabricated form polyaniline with high molecular weight shows conducting behavior similar to metal or semiconductor in different temperature. Solution properties in mcresol chloroform show that PAnCSA is a polyelectrolyte. The factors affecting PAnCSA properties were also discussed.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1997年第6期124-127,共4页
Polymer Materials Science & Engineering
基金
国家自然科学基金
关键词
聚苯胺
掺杂
电解质
结晶度
电导率
樟脑磺酸
polyaniline, solubility in doped state, crystallinite, polyelectrolyte