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聚丙烯腈水增塑熔融纺丝工艺研究 被引量:1

Study on Melt-Spinning Technology of Plasticized Polyacrylonitrile by Hydration
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摘要 研究了聚丙烯腈及其共聚物在水增塑条件下的熔融规律,并在经过改造的φ20mm螺杆熔融纺丝机上进行了纺丝工艺研究。研究表明,聚丙烯腈树脂在一定量的水和热的作用下,由于大分子中氰基之间的作用力被拆散或减弱,可使其变成可进行纺丝成形的增塑熔体;不同含水量、不同组成、不同相对分子质量的聚合体具有不同的水增塑熔点;所纺制的纤维都具有较好的物理机械性能。 The melting law of plasticized polyacrylonitrile and copolyacrylonitrile by hydration and the spinning technology with the reformed φ20 mm extruder have been studied. Since the forces are broken up and reduced between the nitrile groups of polymers, a spinnable and plasticized melt of acrylic resin can be formed with certain water and heat in presence. The melting point of polymers is varied with water contents, components and molecular weight of polymers. The fibres which had been spun have good physical and mechanical properties.
出处 《中国纺织大学学报》 CSCD 1997年第3期13-18,共6页 Journal of China Textile University
关键词 聚丙烯腈纤维 水合增塑 熔融纺丝 工艺 polyacrlonitrile, acrylic fibre, plasticized melt by hydration, melt spinning
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参考文献1

  • 1董纪震,合成纤维生产工艺学,1981年,355页

同被引文献12

  • 1KORTE S.Polymer Handbook[M].New York:John Wiley,1999.
  • 2RANGARAJAN P,BHANU V A,GODSHALL D,et al.Dynamic oscillary shear properties of potentially melt processable high acrylonitrile terpolymers[J].Polymer,2002,43:2 699-2 709.
  • 3KIM B C,MIN B G,SON T W,et al.A study on the hydrated acrylic polymers[J].Polymer International,1995,37(3):191-195.
  • 4DALTON S,HEATLEY F,BUDD P M.Thermal stabilization of polyacrylonitrile fibres[J].Polymer,1999,40(20):5 531-5 543.
  • 5GODSHALL D,RANGARAJAN P,BAIRD D G,et al.Incorporation of methyl acrylate in acrylonitrile based copolymers:effects on melting behavior[J].Polymer,2003,44:4 221-4 228.
  • 6MIN B G,SON T W,KIM B C,et al.Plasticization behavior of polyacrylonitrile and characterization of acrylic fiber prepared from the plasticized melt[J].Polymer Journal,1992,24(9):841-848.
  • 7FRUSHOUR B G.Water as a melting point depressant for acrylic polymers[J].Polymer Bull,1982,7(1):1-8.
  • 8BHANU V A,RANGARAJAN P,WILES K,et al.Synthesis and characterization of acrylonitrile methyl acrylate statistical copolymers as melt processable carbon fiber precursors[J].Polymer,2002,43:4 841-4 850.
  • 9GUPTA A K,PALIWAL D K,BAJAJ P.Melting behavior of acrylonitrile polymers[J].Journal of Applied Polymer Science,1998,70:2 703-2 709.
  • 10陈蕾,杨明远,毛萍君.用于熔融纺丝加工的聚丙烯腈树脂的性能研究[J].中国纺织大学学报,1998,24(2):22-25. 被引量:6

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