摘要
综述了无机引发剂引发丙烯腈水相沉淀聚合的反应机理,其特点是在主氧化剂(过硫酸盐或氯酸盐)存在的无机引发体系中,易产生离子型自由基引发丙烯腈的水相沉淀聚合反应。
The initiation mechanism of aqueous deposited polymerization of acrylonitrile initiated by in organic initiators was reviewed. Ionic radicals were easily produced to initiate the aqueous deposited polymerization of acrylonitrile in the presence of main oxidants,such as persulfate and chlorate in the inorganic initiation systems.
出处
《材料工程》
EI
CAS
CSCD
北大核心
2008年第3期77-80,共4页
Journal of Materials Engineering
基金
国家自然科学基金(50673052)
关键词
丙烯腈
水相沉淀聚合
引发机理
acrylonitrile
aqueous deposited polymerization
initiation mechanism
