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Chemical composition and surface charge properties of montmorillonite 被引量:5

Chemical composition and surface charge properties of montmorillonite
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摘要 The effects of the cell parameter and chemical composition on the surface charge properties of five kinds of different colour montmorillonites were studied. The results indicate that the surface isoelectric point(IEP) of the montmorillonite shows positive correlation with the mass fractions of Fe203 and K20, but it has little relation to the mass fractions of other chemical compositions. At around pH=6.8, the surface zeta potential of the montmorillonite shows the negative relationship with the mass fractions of Fe203 and MgO, but it does not linearly correlate to the mass fractions of other chemical compositions. Cell parameter(bo) of the montmorillonite expresses negative linear relationship with mass fractions of K2O and Na2O, so does cosinβ with mass fractions of SlOE and Fe2O3. And there is no specific relationship between bo and IEP of different montmorillonites, but there is positive correlation between cosinβ and IEP of different montmorillonite samples. The effects of the cell parameter and chemical composition on the surface charge properties of five kinds of different colour montmorillonites were studied.The results indicate that the surface isoelectric point(IEP) of the montmorillonite shows positive correlation with the mass fractions of Fe2O3 and K2O,but it has little relation to the mass fractions of other chemical compositions.At around pH=6.8,the surface zeta potential of the montmorillonite shows the negative relationship with the mass fractions of Fe2O3 and MgO,but it does not linearly correlate to the mass fractions of other chemical compositions.Cell parameter(b0) of the montmorillonite expresses negative linear relationship with mass fractions of K2O and Na2O,so does c0sin β with mass fractions of SiO2 and Fe2O3.And there is no specific relationship between b0 and IEP of different montmorillonites,but there is positive correlation between c0sinβ and IEP of different montmorillonite samples.
出处 《Journal of Central South University of Technology》 EI 2008年第2期193-197,共5页 中南工业大学学报(英文版)
基金 Project(2005CB623701) supported by the Major State Basic Research Development Program of China
关键词 surface charge property zeta potential cell parameter MONTMORILLONITE 表面电荷 势能 单位参数 蒙脱石
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