摘要
研究了 １８种新合成的有机锡化合物的电子轰击质谱，利用Ｂ／Ｅ联动扫描及碰撞诱 导解离技术，研究了该类化合物的几种特殊的重排反应机理，同时探讨了与锡配位的基因 对其断裂规律的影响。
The electron impact mass spectra of eighteen tricyclohexanyl-and triphenyl-tin compounds were reported. The rearrangement mechanism was emphasized and discussed by means of magnetic field/electric field linked scan and collision-induced dissociation. The effect of ligands coordinated with tin on the fragmentation was also described.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1997年第6期675-678,共4页
Chinese Journal of Analytical Chemistry
基金
吉林省科委青年基金资助项目
关键词
三环己基锡
三苯基锡
重排反应
配位效应
质谱
Tricyclohexanyl-tin, triphenyl-tin, collision-induced dissociation, rearrangement reaction, ligand effect
