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SPS夹层用高硬度聚氨酯弹性体的研制 被引量:6

Study on the High Hardness Polyurethane Elastomer Used for the Steel-Polyurethane-Steel Plate Composite
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摘要 采用一步法工艺,对用于聚氨酯夹层板结构的高硬度聚氨酯弹性体进行了研究,分别考察了硬段含量、软段结构以及催化剂等对聚氨酯弹性体力学性能及工艺性能的影响。结果表明,使用自制的CA-1催化剂、混合聚醚多元醇和粗MDI体系,硬段质量分数为50%时,合成的聚氨酯弹性体邵D硬度达75、拉伸强度为26MPa、撕裂强度98kN/m、伸长率为90%、釜中寿命为9min左右,外观无气泡、开裂等缺陷,具有成本低、工艺简单、效率高的优点。 High hardness polyurethane elastomer used for steel-polyurethane-steel composite was studied by one-step method. The fluences of hard segment content, soft segment structure, catalyst on the mechanical and processing properties of the polyurethane elastomer were respectively discussed, The results showed polyurethane elastomer hardness was shore D75, tensile strength was 26 MPa, peel strength was 98 kN/m, elongation was 90%, operation life was about 9 min when using self-produced CA-1 catalyzer, mixed polyether polyol, crude MDI and hard segment content was 50%. It hadn't bubble and crack on surface and had excellence of low cost, simple technique and high efficiency.
出处 《聚氨酯工业》 2008年第1期35-37,共3页 Polyurethane Industry
关键词 夹层板 高硬度 聚氨酯弹性体 polyurethane steel-polyurethane-steel plate composite high hardness
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参考文献5

  • 1Reed D. Revolution in shipping(new polyurethane composite). Urethanes Technology, 2001 (2) : 15
  • 2Kennedy, Stephen J. Composite Steel Structural Plastic Sandwich Plate Systems. US P 0158562(2005)
  • 3Brooking M A, Kennedy S J. The Performance, Safety and Production Benefits of SPS Structures for Double Hull Tankers. Glasgow College of Nautical Studies, January 2005
  • 4陈海良,张芳,孙青峰,朱孔秀,代金辉.聚醚型高硬度聚氨酯弹性体的研制[J].聚氨酯工业,2003,18(4):22-24. 被引量:7
  • 5Lloyd's Register. Provisional rules for the application of sandwich panel construction to ship structure. April 2006

二级参考文献2

  • 1山西化工研究所.聚氨酯弹性体手册[M].北京:化学工业出版社,2001..
  • 2赫普伯恩(英) 高景晨译.聚氨酯弹性体[M].北京:烃加工出版社,1987.181.

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