摘要
采用土柱淋溶方法,以溴离子为示踪离子,研究了蚯蚓活动形成的土壤大孔隙对铜和锌离子在土柱中迁移行为的影响.运用平衡和非平衡对流-弥散模型对溴离子和铜、锌离子在不同土柱中的穿透曲线进行拟合.结果表明,蚯蚓活动形成的蚯蚓孔能够产生明显的优势流现象,这种优势流极大地加快了重金属离子在土柱中垂直向下迁移的速度.非平衡对流-弥散模型能很好地预测溴离子和铜、锌离子在蚯蚓孔土柱中的流出趋势,而平衡对流-弥散模型适合于预测溶质在对照(匀质)土柱中的流出趋势.
Effects of earthworm activity on the soil macropore and preferential solute transport were investigated by applying a bromide tracer. The preferential flow of heavy metals( Cu^2+ and Zn^2+ )was evaluated by equilibrium and non-equilibrium convective-dispersion equation(CDE). Results suggested that macropore formed by earthworm induced a great preferential flow and enhanced the vertical transport of heavy metals. Non-equilibrium CDE could be used to describe the transport of Br-, Cu^2+ and Zn^2+ in both homogeneous and heterogeneous soil columns, while the equilibrium CDE was only valid for homogeneous condition.
出处
《环境化学》
CAS
CSCD
北大核心
2007年第6期768-773,共6页
Environmental Chemistry
基金
国家自然科学基金重点基金(No.20237010)
关键词
蚯蚓
重金属
淋溶
对流-弥散模型
earthworm, heavy metals, leaching behavior, convective-dispersion equation.