摘要
Highly regioselective homocoupling of N,N-dialkylanilines can be achieved in water with cerium reagents, in which various N,N,N′,N′-tetraalkylbenzidines are obtained from N,N-dialkylanilines either by direct oxidation by cerium(Ⅳ)reagents or by cerium(Ⅲ) reagents in the presence of hydroperoxide.
Highly regioselective homocoupling of N,N-dialkylanilines can be achieved in water with cerium reagents, in which various N,N,N′,N′-tetraalkylbenzidines are obtained from N,N-dialkylanilines either by direct oxidation by cerium(Ⅳ)reagents or by cerium(Ⅲ) reagents in the presence of hydroperoxide.
基金
Supported by the National Natural Science Foundation of China(Nos20572058 and 20372041)
Beijing Department of Education(NoXK100030514)