过渡金属配合物氧化还原反应中的电子转移轨道理论的研究及应用

Study on Electron Transfer Orbital Theory in the Oxidation-reduction Reaction of Transition Metal Coordination Complex with Applicatins

提出了过渡金属配合物氧化还原反应中的电子转移轨道理论,应用该理论能更好地研究外界机理和内界机理的过度态结构、电子转移轨道和反应速率.

In this paper, the electron transfer orbital theory in the oxidation-reduction reaction of coor-dination complex is put forward. With this theory, one can researh the structure,transition state,electron transfer orbital and rate of coordination complexes better.