摘要
以Cl3CCOOH、1,10-菲罗啉为配体,以MnCl2·4H2O为金属离子盐,通过溶液蒸发法合成了具有纳米级金属骨架的三元配合物Mn(C2Cl3O2)Cl(C12H8N2)2。通过元素分析、红外光谱、X单晶衍射测得配合物属于单斜晶系,其空间群为P21/c,a=1.8155nm,b=1.0638nm,c=1.4685nm,β=112.9°,z=4,V=2.6110nm3。通过纳米化计算的方法,计算出总晶胞数、总原子数、及表面参数随粒径变化的关系,得出Mn(C2Cl3O2)Cl(C12H8N2)2最佳纳米化尺度为115nm。
The trinuclear zinc（II） complex Mn（C2Cl3O2）Cl（C12H8N2）2 was synthesized and structurally characterized by single crystal X-ray diffraction method. The data showed that theMn（C2Cl3O2）Cl（C12H8N2）2complex belonged to the monoclinic crystal system, the crystal data was a= 1.815 5 nm, b= 1.063 8 nm, c= 1.468 5 nm,β= 112.9°, z=4, V=2.6 J 1 0 nm^3. On the basis of the crystal structure of the title compound ,the crystal cell numbers, atomicity, surface layer atomicity and its proportion were assumed. And the computation discussion to turning compounds into nano-meter particle was theoretically carried on. The optimum dimension of its nanoparticle is theroretically assured to be about 115 nm.
出处
《中国粉体技术》
CAS
2008年第2期18-21,共4页
China Powder Science and Technology
基金
中国地质大学第六届“挑战杯”课外学术科技作品竞赛资助项目(编号:cugtzb0704)
中国地质大学创新人才资助项目
