摘要
采用水热法,以十六烷三甲基溴化氨(C16TAB)作为表面活性剂,在填充度为75%和温度180℃的条件下,制备了ZnS:Mn的纳米发光粉体.利用激发光谱、发射光谱和透射电子显微镜对其光学特性和形貌进行了研究.实验发现,与未进行表面修饰的ZnS:Mn纳米粒子相比,ZnS:Mn纳米颗粒发光亮度增加数倍,而且随着表面活性剂浓度的增加,ZnS:Mn发光强度显著增强.当质量比m(C16TAB)∶m(Zn)=1∶5时,发光强度达到最大,粒径分布均匀,呈球形,平均粒度为50 nm.
ZnS:Mn nano-sized powders were synthesized hy hydrothermal method, using C16TAB as surfactant, the fill factor was 75%, reaction temperature of 180℃. The optical properties and the morphology of ZnS: Mn are studied by exssion spectra, emssion spectra and transmission electron microscopy(TEM). The result indicated that the uncoated ZnS:Mn nanoparticles is much stronger than that in surfactant ones. With C16TAB concentration increasing, the luminescent intensity of ZnS:Mn grew strong. When m (C16 TAB ):m (Zn) was 1/5, the mast luminescent intensity was achieved. It is found that the particles of ZnS:Mn exposed ferrite has an average size of 50nm. Key words: hydrothermal; surfactant; luminescent power
出处
《河北大学学报(自然科学版)》
CAS
北大核心
2008年第2期147-151,共5页
Journal of Hebei University(Natural Science Edition)
基金
河北省自然科学基金资助项目(E2006001008
E2007000197)
关键词
水热法
表面活性剂
发光粉体
hydrothermal
surfactant
luminescent power