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新型聚醚季铵盐PECH-QL的合成与表征 被引量：2

Synthesis and Characterization of Novel Polyether Quaternary Ammonium Salt PECH-QL
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摘要 以聚环氧氯丙烷(PECH)为原料,用喹啉(QL)作季铵化试剂,合成了一种新型的聚醚季铵盐(PECH-QL)。考察了反应时间、反应温度和反应物配比对聚环氧氯丙烷接枝率的影响;用红外光谱和元素分析仪对聚醚季铵盐进行了表征。 The synthesis of novel polyether quaternary ammonium salt (PECH-QL) with ether bond in the main chain of polymer and the base group of quaternary ammonium in the side chain of polymer was presented in this paper.The influence of reaction temperature,reaction time and reactive mixture ratio on the grafting ratio of PECH was investigated.The optimum reaction conditions were obtained by some experiments as follows:reaction temperature 70~80℃;n(PECH) ∶n(QL)=1∶4;reaction time 7h.The grafting ratio of PECH was 80%.The structure of the PECH-QL was characterized by infrared spectroscopy (IR) and element analysis (EA).
作者 卢敏 刘泽民 王会嫣 张玉清
机构地区 河南科技大学化工与制药学院
出处 《河南科技大学学报（自然科学版）》 CAS 2008年第3期102-104,共3页 Journal of Henan University of Science And Technology:Natural Science
基金 国家"863"项目(2007AA05Z454)
关键词 聚醚 季铵盐 接枝率 Polyether Quaternary ammonium salt Grafting ratio
分类号 TQ326 [化学工程—合成树脂塑料工业]
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参考文献12

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共引文献24

同被引文献28

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引证文献2

二级引证文献2

河南科技大学学报（自然科学版）
2008年 第3期

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