5-[对-(4-甲基亚苄基亚氨基)]-苯基-10,15,20-三苯基卟啉铜(Ⅱ)配合物的合成与性质

Study on properties and synthesis of 5-[p-(4-methylbenzylideneamino)]phenyl-10,15,20-triphenylporphyrin copper (Ⅱ) complex

以吡咯、苯甲醛为原料,经过硝化、还原、缩合等一系列反应合成了5-[对-(4-甲基亚苄基亚氨基)]苯基-10,15,20-三苯基卟啉铜(Ⅱ)配合物,通过FT-IR、UV-vis、FAB-MS及1H NMR对产物进行了表征,并对化合物的发光性能和热稳定性进行了研究,实验结果显示其最大发光波长为650nm,位于可见光中的红光区;化合物在空气中初始分解温度为70℃。

5-[-p-（4-methylbenzylideneamino）]phenyl-10,15,20-triphenylporphyrin copper（Ⅱ ） omplex was designed and synthesized by the reaction of pyrrole and benzaldehyde. The intermediates and target compounds were characterized by IR spectra, UV-vis spectra, FAB-MS and 1H NMR. Furthermore, we studied the thermostability and luminescent effect of the target compound. The experiment showed that the strongest luminescent wavelength was 650nm, which located in visible light area. The compound decomposed at 70℃ in the air.