摘要
聚苯乙烯磺酸钠(PSSS)/L-谷氨酸(L-Glu)二元体系中,利用缓慢扩散的CO2与在有机-无机界面上富集的钙离子相结合,合成了碳酸钙微球。实验表明,PSSS/L-Glu浓度比对碳酸钙晶体的形貌和晶型有着重要影响。通过改变实验条件,还得到了菱形和立方形晶体。取向聚积理论很好地解释了微球晶体的形成。PSSS/L-Glu间的协同作用在晶体化过程中发挥着重要作用。通过X射线粉末衍射仪、透射电镜、扫描电子显微镜等分析手段对产物进行了表征。
Calcium carbonate microspheres were synthesized using enriched Ca2+ ions at organic-inorganic interfaces with the slowly infused COp gas in a system of poly ( sodium 4-styene-sulfonate) (PSSS)/L-Glutamic acid (L-Glu). The experiments showed that the concentration ratio between PSSS and L-Glu played important roles in the morphology and polymorph of calcium carbonate. Crystals with rectangle-like and cube-like morphology were obtained besides microspheres by adjusting the experimental parameters. The oriented aggregation mechanism accounted for the formation process of the microsphere crystals. The synergistic effect of PSSS and L-Glu was considered to play an important part in the crystalliza- tion~ The products were characterized by X-ray powder diffraction, transmission electron microscopy, and scanning electron microscopy.
出处
《化工新型材料》
CAS
CSCD
北大核心
2008年第4期32-33,49,共3页
New Chemical Materials
基金
国家自然科学基金(批准号:20171001)
安徽省教育厅自然科学基金(批准号:2005KJ369ZC)资助
关键词
协同作用
微球
碳酸钙
晶体增长
synergistic effect, microsphere, calcium carbonate, crystal growth