摘要
报道了一种高效、温和、对底物有较广泛适用性的苯甲醛氧化酯化反应的催化体系.以双氧水为氧化剂,在较温和的反应条件下,S·SnO_2/HMS催化剂可以有效地催化苯甲醛的氧化酯化反应.催化剂易于从反应体系中分离,可以重复利用.
A highly efficient and mild procedure has been described for the oxidation of benzaldehyde to corresponding esters in alcohols with S.SnO2/HMS as catalyst and H2O2 as oxidant. This catalytic system can be used in the preparation of a broad range of esters. Moreover, S-SnO2/HMS catalyst can be easily separated from the reaction system and reused several times.
出处
《兰州大学学报(自然科学版)》
CAS
CSCD
北大核心
2008年第2期86-88,91,共4页
Journal of Lanzhou University(Natural Sciences)
关键词
苯甲醛
HMS
中孔分子筛
氧化
酯化
benzaldehyde
HMS
mesoporous molecular sieve
oxidation
esterification