烯甲酰化反应及其立体化学的再研究

Camphene Formylation and the Study of Stereochemistry Once Again

用ＤＭＦＳＯＣｌ２和ＤＭＦＰＯＣｌ３均能使莰烯甲酰化，所得ω甲酰基莰烯中均以Ｅ型异构体为主．随着甲酰化反应温度降低，Ｚ型ω甲酰基莰烯的得率有所增加．

:Camphene can be formylated by DMFSOCl2 or DMFPOCl3,Most of the formylcamphene is (E)isomeride.The yield of (Z)formylcamphene is increased in the low formylation temperature.