摘要
应用模拟热谱曲线法，在３０℃和４０℃下水溶液、单一及混合胶束溶液中，研究了用Ｎａ２ＳＯ３－Ｋ２Ｓ２Ｏ８氧化还原体系引发的丙烯酰胺聚合反应．
The kinetics of the polymerization of acrylamide initated by Na2SO3K2S2O8 in aqueous solutions and micellar solutions investigated with the analog thermogram method.A reaction mechanium is suggested and rate equations are derived.The influence of surfactant micelles on the polymerization rate constant and molecular weight of polyacrylamide is discussed.
出处
《四川大学学报（自然科学版）》
CAS
CSCD
北大核心
1997年第6期822-827,共6页
Journal of Sichuan University(Natural Science Edition)
基金
国家自然科学基金
关键词
丙烯酰胺
聚合反应
混合胶束溶液
表面活性剂
polymerization of acrylamide,single and mixed micelles of surfactants,redox initiating system,analog thermogram method,thermokinetics
