相转移催化剂存在下肟类的选择性间接电氧化的研究

A Study of Oxime Was Indirect Electrochemistry Oxidated Selectively on the Phase Transfer Catalyst

以Ｍｎ３＋／Ｍｎ２＋为间接电氧化还原体系，在相转移催化剂ＰｈＣＨ２Ｎ（Ｃ２Ｈ５）３Ｃｌ存在下，对肟类化合物进行选择性间接电氧化．研究结果表明：在一定温度下，肟类化合物能较快地被选择性氧化为相应的羰基化合物，收率为７０％～９０％．

This paper researched that oxime was indirect etectrochemistry oxidated selectively on phase transfer catalyst PhCH2N(C2H5)3Cl in Mn3+/Mn2+ oxidationreduction system.The experimental results showed that the oxime can be oxidated selectively to producting corresponding carbonyl compound and the yield was 70%～90%.